| 1. Identity statement | ||||
| Reference Type | Journal Article | |||
| Site | mtc-m21d.sid.inpe.br | |||
| Holder Code | isadg {BR SPINPE} ibi 8JMKD3MGPCW/3DT298S | |||
| Identifier | 8JMKD3MGP3W34T/476MEQS | |||
| Repository | sid.inpe.br/mtc-m21d/2022/06.27.11.37 (restricted access) | |||
| Last Update | 2022:06.27.11.37.07 (UTC) simone | |||
| Metadata Repository | sid.inpe.br/mtc-m21d/2022/06.27.11.37.07 | |||
| Metadata Last Update | 2023:01.03.16.46.09 (UTC) administrator | |||
| DOI | 10.1016/j.cattod.2021.08.013 | |||
| ISSN | 0920-5861 | |||
| Citation Key | MirandaNuMaPeOkViDo:2022:CoCoHy | |||
| Title | Conversion of Co-Mn-Al hydrotalcites in highly active spinel-type catalysts for peroxide decomposition  | |||
| Year | 2022 | |||
| Month | Aug. | |||
| Access Date | 2024, May 20 | |||
| Type of Work | journal article | |||
| Secondary Type | PRE PI | |||
| Number of Files | 1 | |||
| Size | 5735 KiB | |||
| 2. Context | ||||
| Author | 1 Miranda, André Navarro de 2 Nunes, Willian Gonsalves 3 Maschio, Leandro José 4 Pereira, Luís Gustavo Ferroni 5 Okamoto, Sayuri 6 Vieira, Ricardo 7 Doubek, Gustavo | |||
| Resume Identifier | 1 2 3 4 5 6 8JMKD3MGP5W/3C9JJ68 | |||
| Group | 1 2 3 PCP-ETES-DIPGR-INPE-MCTI-GOV-BR 4 PCP-ETES-DIPGR-INPE-MCTI-GOV-BR 5 COPDT-CGIP-INPE-MCTI-GOV-BR 6 COPDT-CGIP-INPE-MCTI-GOV-BR | |||
| Affiliation | 1 Universidade Estadual de Campinas (UNICAMP) 2 Universidade Estadual de Campinas (UNICAMP) 3 Instituto Nacional de Pesquisas Espaciais (INPE) 4 Instituto Nacional de Pesquisas Espaciais (INPE) 5 Instituto Nacional de Pesquisas Espaciais (INPE) 6 Instituto Nacional de Pesquisas Espaciais (INPE) 7 Universidade Estadual de Campinas (UNICAMP) | |||
| Author e-Mail Address | 1 2 3 4 5 sayokamoto@hotmail.com 6 ricardo.vieira@inpe.br 7 doubek@unicamp.br | |||
| Journal | Catalysis Today | |||
| Volume | 397 | |||
| Pages | 365-374 | |||
| Secondary Mark | A1_INTERDISCIPLINAR A1_ENGENHARIAS_III A1_ENGENHARIAS_II A1_ENGENHARIAS_I A1_CIÊNCIAS_AGRÁRIAS_I A1_BIODIVERSIDADE A2_QUÍMICA A2_MATERIAIS A2_GEOCIÊNCIAS A2_BIOTECNOLOGIA B1_CIÊNCIAS_AMBIENTAIS B2_ASTRONOMIA_/_FÍSICA | |||
| History (UTC) | 2022-06-27 11:37:07 :: simone -> administrator :: 2022-06-27 11:37:08 :: administrator -> simone :: 2022 2022-06-27 11:37:26 :: simone -> administrator :: 2022 2023-01-03 16:46:09 :: administrator -> simone :: 2022 | |||
| 3. Content and structure | ||||
| Is the master or a copy? | is the master | |||
| Content Stage | completed | |||
| Transferable | 1 | |||
| Content Type | External Contribution | |||
| Version Type | publisher | |||
| Keywords | Peroxide decomposition Spinel Catalyst Li-O2 battery Micro-thruster | |||
| Abstract | The fast decomposition of peroxides (M2O2, where M = H+, Li+) at room temperature has gained increased attention given its relevance, from propulsive systems to metal-O2 conversion batteries. This study describes, by a rational design of experiment, the influence of selected parameters such as: pH, initial concentration of K2CO3, precipitate aging, precipitate washing, and thermal treatment for the hydrotalcite co-precipitation, characterizing it for each synthesis variable. The results show that hydrotalcites can efficiently be converted in Co-Mn-Al spinels and as a result, a new highly active Co2Mn0.5Al0.5O4 spinel oxide was synthesized after thermal treatment. Its activity and mechanical resistance were tested in a micro-thruster reactor where it showed total decomposition (> 98%) of H2O2 and in a Li-O2 battery, with increased cyclability, been able to reduce the charging potential in ~200 mV. These encouraging results enhance the importance not only of this class of material, but also, the importance of robust synthesis methodologies for reproducible results. | |||
| Area | COMB | |||
| Arrangement 1 | urlib.net > BDMCI > Fonds > Produção pgr ATUAIS > PCP > Conversion of Co-Mn-Al... | |||
| Arrangement 2 | urlib.net > BDMCI > Fonds > Produção a partir de 2021 > CGIP > Conversion of Co-Mn-Al... | |||
| doc Directory Content | access | |||
| source Directory Content | there are no files | |||
| agreement Directory Content |
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| 4. Conditions of access and use | ||||
| Language | en | |||
| Target File | 1-s2.0-S0920586121003692-main.pdf | |||
| User Group | simone | |||
| Reader Group | administrator simone | |||
| Visibility | shown | |||
| Archiving Policy | denypublisher denyfinaldraft24 | |||
| Read Permission | deny from all and allow from 150.163 | |||
| Update Permission | not transferred | |||
| 5. Allied materials | ||||
| Next Higher Units | 8JMKD3MGPCW/3F35D8B 8JMKD3MGPCW/46KUES5 | |||
| Citing Item List | sid.inpe.br/mtc-m21/2012/07.13.14.59.12 2 sid.inpe.br/bibdigital/2022/04.03.23.11 2 | |||
| Dissemination | WEBSCI; PORTALCAPES. | |||
| Host Collection | urlib.net/www/2021/06.04.03.40 | |||
| 6. Notes | ||||
| Empty Fields | alternatejournal archivist callnumber copyholder copyright creatorhistory descriptionlevel e-mailaddress format isbn label lineage mark mirrorrepository nextedition notes number orcid parameterlist parentrepositories previousedition previouslowerunit progress project rightsholder schedulinginformation secondarydate secondarykey session shorttitle sponsor subject tertiarymark tertiarytype url | |||
| 7. Description control | ||||
| e-Mail (login) | simone | |||
| update | ||||